Home > Aminoacid Compounds> (2S,3R,4R,5R)-3,4,5-trihydroxypiperidine-2-carboxylic acid

(2S,3R,4R,5R)-3,4,5-trihydroxypiperidine-2-carboxylic acid

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Origin: China

Cas No: 113000-77-4

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 50 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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CAS No.: 113000-77-4 Formula: C6H11NO5 Molecular Weight: 177.15500

Basic Info

Chemical Name	(2S,3R,4R,5R)-3,4,5-trihydroxypiperidine-2-carboxylic acid
Synonyms	2-Piperidinecarboxylic acid,3,4,5-trihydroxy-,(2S-(2alpha,3beta,4alpha,5alpha)); 2,6-dideoxy-2,6-imino-D-mannonic acid; 2-Piperidinecarboxylic acid,3,4,5-trihydroxy-,[2S-(2a,3b,4a,5a)]; ZHFMVVUVCALAMY-KKQCNMDGSA; 2S,3R,4R,5R-3,4,5-Trihydroxypipecolic acid; 1-deoxy-5-aza-D-allopyran-uronic acid;
CAS No.	113000-77-4
Molecular Formula	C6H11NO5
Molecular Weight	177.15500
PSA	110.02000
LogP	-2.54570

Properties

Density	1.676g/cm3
Boiling Point	442.1ºC at 760mmHg
Flash Point	221.1ºC
Refractive Index	1.623
Vapor Pressure	1.13E-09mmHg at 25°C

Synthesis Route

(2S,3R,4R,5R)-1-tert-butyl 2-ethyl 3,4,5-trihydroxypiperidine-1,2-dicarboxylate→(2S,3R,4R,5R)-3,4,5-trihydroxypiperidine-2-carboxylic acid
(2S,3R,4R,5R)-methyl 2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-D-mannonate→(2S,3R,4R,5R)-3,4,5-trihydroxypiperidine-2-carboxylic acid
N-benzyloxycarbonyl-3-O-benzyl-2,6-dideoxy-2,6-imino-D-mannurono-1,4-lactone→(2S,3R,4R,5R)-3,4,5-trihydroxypiperidine-2-carboxylic acid

Precursor

methyl N-benzyloxycarbonyl-3-O-benzyl-2,6-dideoxy-2,6-imino-α-D-mannofuranoside
(2S,3R,4R,5R)-1-tert-butyl 2-ethyl 3,4,5-trihydroxypiperidine-1,2-dicarboxylate
(2S,3R,4R,5R)-methyl 2,6-dideoxy-2,6-imino-3,4-O-isopropylidene-D-mannonate
N-benzyloxycarbonyl-3-O-benzyl-2,6-dideoxy-2,6-imino-D-mannurono-1,4-lactone

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