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Home > Chiral Compounds> (3S)-4-(9H-fluoren-9-ylmethoxycarbonyl)morpholine-3-carboxylic acid
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(3S)-4-(9H-fluoren-9-ylmethoxycarbonyl)morpholine-3-carboxylic acid

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Origin: China

Cas No: 281655-37-6

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 100 mt/month

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  • Products Specification
  • Product Description

  • Property

    CAS No.: 281655-37-6 Formula: C20H19NO5 Molecular Weight: 353.36900

    Description

    4-Fmoc-3(S)-morpholinecarboxylic Acid is used to prepare heterocyclic core analogs of a direct thrombin inhibitor.

    Basic Info

    Chemical Name (3S)-4-(9H-fluoren-9-ylmethoxycarbonyl)morpholine-3-carboxylic acid
    Synonyms

    4-Fmoc-3(S)-morpholine carboxylic acid;
    FMOC-S-MORPH-OH;
    (S)-4-N-Fmoc-3-morpholinecarboxylic acid;
    FMOC-S-MO3C-OH;
    Fmoc-L-Mor-OH;

    CAS No. 281655-37-6
    Molecular Formula C20H19NO5
    Molecular Weight 353.36900
    PSA 76.07000
    LogP 2.65880

    Properties

    Density 1.344g/cm3
    Boiling Point 579.8ºC at 760mmHg
    Flash Point 304.4ºC
    Refractive Index 1.621
    Vapor Pressure 2.77E-14mmHg at 25°C

    Synthesis Route

    (3S)-4-[(2-methylpropan-2-yl)oxycarbonyl]morpholine-3-carboxylic acid+9H-fluoren-9-ylmethyl carbonochloridate→(3S)-4-(9H-fluoren-9-ylmethoxycarbonyl)morpholine-3-carboxylic acid
    (3S)-2,3-dihydro[1,4]oxazine-3,4-dicarboxylic acid 4-(9H-fluoren-9-ylmethyl) ester 3-methyl ester→(3S)-4-(9H-fluoren-9-ylmethoxycarbonyl)morpholine-3-carboxylic acid
    (2S)-2-[(2,2-dimethoxyethylamino)(9H-fluoren-9-ylmethoxycarbonyl)amino]-3-hydroxypropionic acid methyl ester→(3S)-4-(9H-fluoren-9-ylmethoxycarbonyl)morpholine-3-carboxylic acid

    Precursor

    (3S)-2,3-dihydro[1,4]oxazine-3,4-dicarboxylic acid 4-(9H-fluoren-9-ylmethyl) ester 3-methyl ester
    9H-fluoren-9-ylmethyl carbonochloridate
    (2S)-2-[(2,2-dimethoxyethylamino)(9H-fluoren-9-ylmethoxycarbonyl)amino]-3-hydroxypropionic acid methyl ester
    (3S)-4-[(2-methylpropan-2-yl)oxycarbonyl]morpholine-3-carboxylic acid

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