Home > Chiral Compounds> (3R,4R,5R)-5-(hydroxymethyl)piperidine-3,4-diol

(3R,4R,5R)-5-(hydroxymethyl)piperidine-3,4-diol

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Origin: China

Cas No: 169105-89-9

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 50 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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CAS No.: 169105-89-9 Formula: C6H14ClNO3 Molecular Weight: 183.63300

Basic Info

Chemical Name	(3R,4R,5R)-5-(hydroxymethyl)piperidine-3,4-diol
Synonyms	IFM; 5-HYDROXYMETHYL-3,4-DIHYDROXYPIPERIDINE; iso-Fagomine; 1oif; D-Isofagomine; Afegostat;
CAS No.	169105-89-9
Molecular Formula	C6H14ClNO3
Molecular Weight	183.63300
PSA	72.72000
LogP	-0.94930

Properties

Appearance & Physical State	yellow low-melting solid
Density	1.279g/cm3
Boiling Point	317.2ºC at 760mmHg
Flash Point	171.8ºC
Refractive Index	1.535
Vapor Pressure	0mmHg at 25°C

Synthesis Route

N-benzyl (+)-isofagomine→(3R,4R,5R)-5-(hydroxymethyl)piperidine-3,4-diol
benzyl 4-cyano-4-deoxy-2,3-O-isopropylidene-β-D-arabinopyranoside→(3R,4R,5R)-5-(hydroxymethyl)piperidine-3,4-diol
(3R,4R,5S)-N-tert-butoxycarbonyl-3-(tert-butyldiphenylsilyloxy)-4-hydroxy-5-(hydroxymethyl)piperidine→(3R,4R,5R)-5-(hydroxymethyl)piperidine-3,4-diol

Precursor

(3R,4R,5R)-phenyl 3,4-dihydroxy-5-(hydroxymethyl)piperidine-1-carboxylate
(3R,4R,5S)-N-tert-butoxycarbonyl-3-(tert-butyldiphenylsilyloxy)-4-hydroxy-5-(hydroxymethyl)piperidine
N-benzyl (+)-isofagomine
benzyl 4-cyano-4-deoxy-2,3-O-isopropylidene-β-D-arabinopyranoside

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