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Glycerol Alpha-Monoallyl Ether

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Origin: China

Cas No: 123-34-2

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 50 mt/month

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  • Products Specification
  • Product Description

  • Property

    CAS No.: 123-34-2 Formula: C6H12O3 Molecular Weight: 132.15800

    Basic Info

    Chemical Name Glycerol Alpha-Monoallyl Ether
    Synonyms

    Glycerol-1-allylether;
    Glycerol α-Monoallyl Ether;
    3-prop-2-enoxypropane-1,2-diol;
    3-ALLYLOXY-1,2-PROPANEDIOL;

    CAS No. 123-34-2
    Molecular Formula C6H12O3
    Molecular Weight 132.15800
    PSA 49.69000
    LogP -0.45780

    Properties

    Appearance & Physical State clear, colorless liquid.
    Density 1.068 g/mL at 25ºC(lit.)
    Boiling Point 142ºC28 mm Hg(lit.)
    Melting Point -100ºC
    Flash Point 132ºC
    Refractive Index n20/D 1.462(lit.)
    Vapor Pressure 0.00991mmHg at 25°C

    Safety Info

    RTECS TY2700000
    Safety Statements S26
    HS Code 2909499000
    WGK Germany 1
    Risk Statements R36
    Hazard Codes Xi

    Synthesis Route

    Methanol+4-(prop-2-enoxymethyl)-1,3-dioxolan-2-one→Glycerol Alpha-Monoallyl Ether+dimethyl carbonate
    methyl prop-2-enyl carbonate+glycerol→Glycerol 1,2-Carbonate+4-(prop-2-enoxymethyl)-1,3-dioxolan-2-one
    bis(prop-2-enyl) carbonate+glycerol→Glycerol 1,2-Carbonate+4-(prop-2-enoxymethyl)-1,3-dioxolan-2-one

    Toxicity

    Exposure Route Type of Test Species Observed Dose/Duration Toxic Effects
    Administration onto the skin Standard Draize test Rodent - rabbit 535 mg/24H -
    Administration into the eye Standard Draize test Rodent - rabbit 107 mg -
    Administration into the eye Standard Draize test Rodent - rabbit 100 mg/24H -

    Precursor

    Allyl bromide
    glycerol
    Allyl glycidyl ether
    2,2-dimethyl-4-(prop-2-enoxymethyl)-1,3-dioxolane

    Downstream Product

    [2-(4-methylphenyl)sulfonyloxy-3-prop-2-enoxypropyl] 4-methylbenzenesulfonate
    4-(prop-2-enoxymethyl)-1,3-dioxolan-2-one
    5-methyl-3,6,8-trioxabicyclo[3.2.1]octane
    2-phenyl-4-(prop-2-enoxymethyl)-1,3-dioxolane

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