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dioxygen

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Origin: China

Cas No: 7782-44-7

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  • Products Specification
  • Product Description
  • Property

    CAS No.: 7782-44-7 Formula: O2 Molecular Weight: 31.99880

    Description

    Triplet oxygen, systematically but less commonly, 1,2-dioxidanediyl, is normal, gaseous oxygen (O2, dioxygen) in its ground state. It is therefore classified as an inorganic chemical, and more specifically as a particular electronic state of one allotrope of the inorganic chemical element, oxygen. In this particular state, according to one type of modern bonding theory, the electron configuration of the oxygen molecule has two electrons occupying two molecular orbitals (MOs) of equal energy (that is, degenerate MOs), therefore remaining unpaired. These orbitals are classified as antibonding and are of higher energy, so the resulting bonding structure between the oxygen atoms is weakened (i.e., is higher in energy)—for instance, it is higher in energy than the bonding in dinitrogen, where the corresponding antibonding orbitals are empty. The spectroscopic molecular term symbol for triplet (ground state) oxygen is 3Σ− g.[bettersourceneeded]

    Basic Info

    Chemical Name dioxygen
    Synonyms

    oxygen-16;
    peroxide radical;
    Oxygen;
    hyperoxia;
    hydroperoxide radical;
    oxygengas;
    hydroperoxo radical;
    oxigeno;
    hydroperoxyl radical;
    lox;
    oxygene;
    perhydroxyl radical;
    pureoxygen;
    hydroperoxy radical;
    Dioxygen;
    peroxyl radical;

    CAS No. 7782-44-7
    Molecular Formula O2
    Molecular Weight 31.99880
    PSA 34.14000
    LogP 0.06700

    Properties

    Appearance & Physical State colourless gas
    Density 1.429(0ºC)
    Boiling Point -183ºC
    Melting Point -218ºC
    Flash Point none
    Refractive Index 1.776
    Stability Stable. Vigorously supports combustion. Incompatible with phosphorus, organic materials, many powdered metals.
    Vapor Density 1.11 (vs air)
    Vapor Pressure 3.27E-25mmHg at 25°C

    Safety Info

    RTECS RS2060000
    Hazard Class 2.2
    Safety Statements S17
    HS Code 2804400000
    WGK Germany -
    RIDADR UN 1014/1072
    Risk Statements R8
    Hazard Codes O
    Caution Statement P220; P410 + P403
    Signal Word Danger
    Symbol GHS03, GHS04
    Hazard Declaration H270; H280

    Synthesis Route

    DO radical+hydrogen peroxidedeuterium hydrogen oxide+dioxygen
    CH3ReO(η2-O2)2(H2O)dioxygen+Methyltrioxorhenium (VII)
    hydrogen peroxidedioxygen

    Toxicity

    Exposure Route Type of Test Species Observed Dose/Duration Toxic Effects
    Inhalation TCLo - Lowest published toxic concentration Human 100 pph/14H 1.Lungs, Thorax, or Respiration-cough
    2.Lungs, Thorax, or Respiration-other changes
    Inhalation TCLo - Lowest published toxic concentration Human - woman 12 pph/10M,female 26-39 week(s) after conception 1.Reproductive-Specific Developmental Abnormalities-cardiovascular (circulatory) system
    Inhalation TCLo - Lowest published toxic concentration Rodent - rat 10 pph/12H,female 22 day(s) after conception 1.Reproductive-Specific Developmental Abnormalities-respiratory system

    Precursor

    ethyl
    Hydrogen gas
    Water
    oxygen

    Downstream Product

    oxirane
    hydroxyl
    dioxygen
    oxidochlorine(•)

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