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Dess-Martin periodinane

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Origin: China

Cas No: 87413-09-0

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 100 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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Products Specification
Product Description

Quick Details
CAS No.:
87413-09-0
Other Names:
87413-09-0
MF:
C13H13IO8
EINECS No.:
87413-09-0
Place of Origin:
Shandong, China
Type:
Agrochemical Intermediates, Dyestuff Intermediates, Flavor & Fragrance Intermediates, Pharmaceutical Intermediates, Syntheses Material Intermediates
Purity:
≥98%
Brand Name:
Finerchem
Model Number:
87413-09-0
Application:
Oxidation reagent
Appearance:
White crystalline powder
Product name:
Dess-Martin periodinane
Molecular Weight:
424.14
Packaging&Delivery
Packaging Details
Liquid product packaging:
1kg/bottle, 25kg/drum, or as your demand
Solid package:
Aluminum foil bag for within 10kg
Fiber drum for 10kg and more
Shipping: By air, by sea or by courier (VIP account of TNT, DHL, Fedex and EMS)
Port
Shanghai Port

Property

CAS No.: 87413-09-0 Formula: C13H13IO8 Molecular Weight: 424.14200

Description

Dess–Martin periodinane (DMP) is a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. This periodinane has several advantages over chromium- and DMSO-based oxidants that include milder conditions (room temperature, neutral pH), shorter reaction times, higher yields, simplified workups, high chemoselectivity, tolerance of sensitive functional groups, and a long shelf life. It is named after the American chemists Daniel Benjamin Dess and James Cullen Martin who developed the reagent in 1983. It is based on IBX, but due to the acetate groups attached to the central iodine atom, DMP is much more reactive than IBX and is much more soluble in organic solvents.

Basic Info

Chemical Name	Dess-Martin periodinane
Synonyms	(1,1-diacetyloxy-3-oxo-1λ<sup>5</sup>,2-benziodoxol-1-yl) acetate;
CAS No.	87413-09-0
Molecular Formula	C13H13IO8
Molecular Weight	424.14200
PSA	105.20000
LogP	1.95370

Properties

Appearance & Physical State	white crystalline powder
Density	1.362
Boiling Point	40ºC
Melting Point	130-133ºC
Flash Point	>221 °F
Storage Condition	0-6ºC

Safety Info

Safety Statements	S17-S23-S24/25-S36/37
WGK Germany	3
RIDADR	UN 1593 6
Risk Statements	R40; R8
Hazard Codes	Xn
Signal Word	Warning
Supplemental Hazard Statements	Risk of explosion if heated under confinement.
Hazard Declaration	H272; H302 + H312 + H332; H315; H319; H335
Caution Statement	P220; P261; P280; P305 + P351 + P338
Symbol	GHS03, GHS07

Synthesis Route

Acetic anhydride+2-Iodoxybenzoic Acid→Dess-Martin periodinane
Acetic anhydride+acetic acid→Dess-Martin periodinane
2-iodobenzoic acid+Acetic anhydride→Dess-Martin periodinane

Precursor

Acetic anhydride
2-Iodoxybenzoic Acid
2-iodobenzoic acid
acetic acid

Downstream Product

1,4-Dimethoxy-6-tetralone
3,4,5-Trimethoxybenzaldehyde
4-Iodoaniline
acetic acid

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