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Chlorobis(cyclooctene)rhodium(I) dimer

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Origin: China

Cas No: 12279-09-3

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  • Products Specification
  • Product Description

  • Property

    CAS No.: 12279-09-3 Formula: C32H56Cl2Rh2 Molecular Weight: 717.50400

    Description

    Chlorobis(cyclooctene)rhodium dimer is an organorhodium compound with the formula Rh2Cl2(C8H14)4, where C8H14 is cis-cyclooctene. Sometimes abbreviated Rh2Cl2(coe)4, it is a red-brown, air-sensitive solid that is a precursor to many other organorhodium compounds and catalysts.
    The complex is prepared by treating an alcohol solution of hydrated rhodium trichloride with cyclooctene at room temperature. The coe ligands are easily displaced by other more basic ligands, more so than the diene ligands in the related complex cyclooctadiene rhodium chloride dimer.

    Basic Info

    Chemical Name Chlorobis(cyclooctene)rhodium(I) dimer
    Synonyms

    Chlorobis(cyclooctene)rhodium(I) Dimer;
    Chlorobis(cyclooctene)rhodium(I),dimer;
    [Rh(coe)2Cl]2;
    cyclooctene,rhodium,dichloride;

    CAS No. 12279-09-3
    Molecular Formula C32H56Cl2Rh2
    Molecular Weight 717.50400
    PSA 0.00000
    LogP 12.96620

    Properties

    Melting Point 190ºC (dec.)
    Storage Condition Freezer

    Safety Info

    Safety Statements S26-S37/39
    Risk Statements R20/21/22; R36/37/38
    Hazard Codes Xn
    Symbol GHS07
    Hazard Declaration H302 + H312 + H332; H315; H319; H335
    Caution Statement P261; P280; P305 + P351 + P338
    Signal Word Warning

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