Home > Organosilicon Compounds> [(Z)-5-[(1R,2S)-2-[tert-butyl(dimethyl)silyl]oxycyclohexyl]pent-2-enyl] 2,4-dichlorobenzoate

[(Z)-5-[(1R,2S)-2-[tert-butyl(dimethyl)silyl]oxycyclohexyl]pent-2-enyl] 2,4-dichlorobenzoate

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Origin: China

Cas No: 101859-38-5

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 100 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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CAS No.: 101859-38-5 Formula: C24H36Cl2O3Si Molecular Weight: 471.53200

Basic Info

Chemical Name	[(Z)-5-[(1R,2S)-2-[tert-butyl(dimethyl)silyl]oxycyclohexyl]pent-2-enyl] 2,4-dichlorobenzoate
Synonyms	Benzoic acid,2,4-dichloro-,5-(2-(((1,1-dimethylethyl)dimethylsilyl)oxy)cyclohexyl)-2-pentenyl ester,(1alpha(Z),2beta); ((Z)-5-((1R,2S)-2-(tert-Butyl(dimethyl)silyl)oxycyclohexyl)pent-2-enyl) 2,4-dichlorobenzoate;
CAS No.	101859-38-5
Molecular Formula	C24H36Cl2O3Si
Molecular Weight	471.53200
PSA	35.53000
LogP	8.06720

Properties

Density	1.1g/cm3
Boiling Point	500.9ºC at 760 mmHg
Flash Point	256.7ºC
Refractive Index	1.521
Vapor Pressure	3.64E-10mmHg at 25°C

Synthesis Route

7-oxabicyclo[4.1.0]heptane→[(Z)-5-[(1R,2S)-2-[tert-butyl(dimethyl)silyl]oxycyclohexyl]pent-2-enyl] 2,4-dichlorobenzoate
syn-2-(but-3-enyl)cyclohexanol→[(Z)-5-[(1R,2S)-2-[tert-butyl(dimethyl)silyl]oxycyclohexyl]pent-2-enyl] 2,4-dichlorobenzoate
[(1R,2S)-2-but-3-enylcyclohexyl]oxy-tert-butyl-dimethylsilane→[(Z)-5-[(1R,2S)-2-[tert-butyl(dimethyl)silyl]oxycyclohexyl]pent-2-enyl] 2,4-dichlorobenzoate

Precursor

syn-2-(but-3-enyl)cyclohexanol
methyl (Z)-5-((1S,2R)-2-((tert-butyldimethylsilyl)oxy)cyclohexyl)pent-2-enoate
3-[(1S,2R)-2-[tert-butyl(dimethyl)silyl]oxycyclohexyl]propanal
7-oxabicyclo[4.1.0]heptane

Downstream Product

2-[(2R,4aR,8aS)-2-hydroxy-3,4,4a,5,6,7,8,8a-octahydrochromen-2-yl]ethyl 2,4-dichlorobenzoate
[(2R)-2-[(4aS,8aR)-3,4,4a,5,6,7,8,8a-octahydro-2H-chromen-2-yl]-2-iodoethyl] 2,4-dichlorobenzoate

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