Home > Organosilicon Compounds> tert-butyl-dimethyl-[[(1R,3R,5R,6R)-6-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptan-5-yl]oxy]silane

tert-butyl-dimethyl-[[(1R,3R,5R,6R)-6-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptan-5-yl]oxy]silane

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Origin: China

Cas No: 121289-19-8

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 80 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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Product Description

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CAS No.: 121289-19-8 Formula: C16H30O2Si Molecular Weight: 282.49400

Description

Intermediate in the preparation of Dihydroxyvitamin D3 and associated metabolites.

Basic Info

Chemical Name	tert-butyl-dimethyl-[[(1R,3R,5R,6R)-6-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptan-5-yl]oxy]silane
Synonyms
CAS No.	121289-19-8
Molecular Formula	C16H30O2Si
Molecular Weight	282.49400
PSA	21.76000
LogP	4.52040

Synthesis Route

(-)-1,6-Epoxyisodihydrocarveol+tert-butyldimethylsilyl chloride→tert-butyl-dimethyl-[[(1R,3R,5R,6R)-6-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptan-5-yl]oxy]silane
p-Menth-8-en-2-one, 1,6-epoxy-, (1R,4R,6R)-(-)-→tert-butyl-dimethyl-[[(1R,3R,5R,6R)-6-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptan-5-yl]oxy]silane
(-)-carvone→tert-butyl-dimethyl-[[(1R,3R,5R,6R)-6-methyl-3-prop-1-en-2-yl-7-oxabicyclo[4.1.0]heptan-5-yl]oxy]silane

Precursor

tert-butyldimethylsilyl chloride
p-Menth-8-en-2-one, 1,6-epoxy-, (1R,4R,6R)-(-)-
(-)-1,6-Epoxyisodihydrocarveol
(-)-carvone

Downstream Product

(1R,2S,4R,6R)-2,4-Bis(tert-butyldimethylsilyloxy)-1-methyl-cyclohexane 1,2-Epoxide

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