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Picture of (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

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Origin: China

Cas No: 76189-55-4

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 50 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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  • Products Specification
  • Product Description
  • Quick Details

    CAS No.:
    76189-55-4
    MF:
    C44H32P2
    EINECS No.:
    76189-55-4
    Place of Origin:
    Shandong, China
    Type:
    Agrochemical Intermediates, Dyestuff Intermediates, Flavor & Fragrance Intermediates, Pharmaceutical Intermediates, Syntheses Material Intermediates
    Purity:
    99.0%min
    Brand Name:
    Finerchem
    Model Number:
    76189-55-4
    Application:
    organic intermediate
    Appearance:
    powder
    CAS:
    76189-55-4
    Standard:
    export standard
    Product website:
    http://www.finerchem.com/pro01en/id/270.html
    Packing:
    10g/bag
    Sample:
    Provide
    Usage:
    organic intermediate
    Brand:
    Finerchem

    Packaging&Delivery

    Packaging Details
    Liquid product packaging:
    1kg/bottle, 25kg/drum, or as your demand
    Solid package:
    Aluminum foil bag for within 10kg
    Fiber drum for 10kg and more
    Shipping: By air, by sea or by courier (VIP account of TNT, DHL, Fedex and EMS)
    Port
    Qingdao or Shanghai
    Lead Time:
    Quantity(Kilograms)1 - 100>100
    Est. Time(days)2To be negotiated
  • Property

    CAS No.: 76189-55-4 Formula: C46H36P2 Molecular Weight: 650.72600

    Description

    BINAP (2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) is an organophosphorus compound. This chiral ligand is widely used in asymmetric synthesis. It consists of a pair of 2-diphenylphosphinonaphthyl groups linked at the 1 and 1´ positions. This C2-symmetric framework lacks a stereogenic atom, but has axial chirality due to restricted rotation (atropisomerism). The barrier to racemization is high due to steric hindrance, which limits rotation about the bond linking the naphthyl rings. The dihedral angle is approximately 90˚.

    Basic Info

    Chemical Name (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
    Synonyms

    (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL;

    CAS No. 76189-55-4
    Molecular Formula C46H36P2
    Molecular Weight 650.72600
    PSA 27.18000
    LogP 10.92580

    Properties

    Appearance & Physical State white to light yellow crystal powder
    Boiling Point 724.3ºC at 760 mmHg
    Melting Point 239-242ºC
    Flash Point 419ºC
    Refractive Index 235 ° (C=0.3, Toluene)
    Water Solubility insoluble
    Storage Condition Room temperature.

    Safety Info

    Safety Statements S26-S37/39
    HS Code 2902909090
    WGK Germany 3
    Risk Statements R36/37/38
    Hazard Codes Xi

    Downstream Product

    [(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]palladium(II) chloride
    Dichloro[(S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

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