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(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

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начало: Китай

Кас Но: 76189-55-4

Спецификация: 99%наименьший

минимальный объем заказа: 1 /kg

снабженческая способность: 50 mt/month

опережающий период: OEM 7 дней, пятно 3 дня

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Quick Details
CAS No.:
76189-55-4
MF:
C44H32P2
EINECS No.:
76189-55-4
Place of Origin:
Shandong, China
Type:
Agrochemical Intermediates, Dyestuff Intermediates, Flavor & Fragrance Intermediates, Pharmaceutical Intermediates, Syntheses Material Intermediates
Purity:
99.0%min
Brand Name:
Finerchem
Model Number:
76189-55-4
Application:
organic intermediate
Appearance:
powder
CAS:
76189-55-4
Standard:
export standard
Product website:
http://www.finerchem.com/pro01en/id/270.html
Packing:
10g/bag
Sample:
Provide
Usage:
organic intermediate
Brand:
Finerchem
Packaging&Delivery
Packaging Details
Liquid product packaging:
1kg/bottle, 25kg/drum, or as your demand
Solid package:
Aluminum foil bag for within 10kg
Fiber drum for 10kg and more
Shipping: By air, by sea or by courier (VIP account of TNT, DHL, Fedex and EMS)
Port
Qingdao or Shanghai
Lead Time:
Quantity(Kilograms) 1 - 100 >100
Est. Time(days) 2 To be negotiated

Property

CAS No.: 76189-55-4 Formula: C46H36P2 Molecular Weight: 650.72600

Description

BINAP (2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) is an organophosphorus compound. This chiral ligand is widely used in asymmetric synthesis. It consists of a pair of 2-diphenylphosphinonaphthyl groups linked at the 1 and 1´ positions. This C2-symmetric framework lacks a stereogenic atom, but has axial chirality due to restricted rotation (atropisomerism). The barrier to racemization is high due to steric hindrance, which limits rotation about the bond linking the naphthyl rings. The dihedral angle is approximately 90˚.

Basic Info

Chemical Name	(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
Synonyms	(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL;
CAS No.	76189-55-4
Molecular Formula	C46H36P2
Molecular Weight	650.72600
PSA	27.18000
LogP	10.92580

Properties

Appearance & Physical State	white to light yellow crystal powder
Boiling Point	724.3ºC at 760 mmHg
Melting Point	239-242ºC
Flash Point	419ºC
Refractive Index	235 ° (C=0.3, Toluene)
Water Solubility	insoluble
Storage Condition	Room temperature.

Safety Info

Safety Statements	S26-S37/39
HS Code	2902909090
WGK Germany	3
Risk Statements	R36/37/38
Hazard Codes	Xi

Downstream Product

[(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]palladium(II) chloride
Dichloro[(S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

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