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perillyl alcohol

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Origin: China

Cas No: 536-59-4

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 50 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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CAS No.: 536-59-4 Formula: C10H16O Molecular Weight: 152.23300

Description

Perillyl alcohol (IUPAC name: [4-(prop-1-en-2-yl)cyclohex-1-en-1-yl]methanol) and its precursor limonene are naturally occurring monocyclic terpenes derived from the mevalonate pathway in plants. Perillyl alcohol can be found in the essential oils of various botanicals, such as lavender, lemongrass, sage, and peppermint. It has a number of manufacturing, household, and medical applications. For example, perillyl alcohol may be used as an ingredient in cleaning products and cosmetics, and as of 2015 it was in development as a potential treatment for people with brain cancer.
Perillyl alcohol is only produced by certain botanicals, not by animals or humans. It is a metabolite of limonene, which itself is formed from geranyl pyrophosphate in the mevalonate pathway. Conversion of limonene to perillyl alcohol is accomplished via hydroxylation by enzymes that belong to the superfamily of cytochrome P450 proteins. Perillyl alcohol can be metabolized further to perillaldehyde (perillyl aldehyde) and perillic acid.

Basic Info

Chemical Name	perillyl alcohol
Synonyms	(4-(prop-1-en-2-yl)cyclohex-1-enyl)carbinol; p-Mentha-1,8-dien-7-ol; L-(-)-Perilly Alcohol; 1-perillalcohol; PERILLA ALCOHOL; perill alcohol; 1,8-p-Menthadien-7-ol; perilla; (4-(Prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol; Perillol; (4-isopropenyl-cyclohex-1-enyl)-methanol; Perillic alcohol; 1-Cyclohexene-1-methanol, 4-(1-methylethenyl)-; Perillyl alcohol; (4-(prop-1-en-2-yl)cyclohex-1-enyl)methanol; DIHYDRO CUMINYL ALCOHOL;
CAS No.	536-59-4
Molecular Formula	C10H16O
Molecular Weight	152.23300
PSA	20.23000
LogP	2.28130

Properties

Appearance & Physical State	clear colorless to light yellow liquid
Density	0.94g/cm3
Boiling Point	241.2ºC at 760mmHg
Flash Point	99.6ºC
Refractive Index	n20/D 1.501(lit.)

Safety Info

RTECS	OS8395000
HS Code	2906199090
WGK Germany	3
Risk Statements	R37/38; R41
Hazard Codes	Xi

Synthesis Route

(4S)-4-prop-1-en-2-ylcyclohexene-1-carbaldehyde→(4-prop-1-en-2-ylcyclohexyl)methanol+
(-)-MYRTENOL→6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptan-3-ol+perillyl alcohol
→(+)-β-Pinene oxide+6,6-Dimethylbicyclo[3.1.1]heptan-2-one

Precursor

(4-prop-1-en-2-ylcyclohexen-1-yl)methyl acetate
(4R)-limonene
perillyl aldehyde
trans-2-methylene-5-isopropylenylcyclohexanol

Downstream Product

(4S)-4-prop-1-en-2-ylcyclohexene-1-carbaldehyde
methyl (4S)-4-(2,2-dimethoxyethyl)-5-methylhex-5-enoate
(4S)-4-prop-1-en-2-ylcyclohexene-1-carboxylic acid
methyl (4S)-4-prop-1-en-2-ylcyclohexene-1-carboxylate

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