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diethyl sulfide

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Origin: China

Cas No: 352-93-2

Specification: 99%min

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  • Products Specification
  • Product Description
  • Property

    CAS No.: 352-93-2 Formula: C4H10S Molecular Weight: 90.18720

    Description

    Diethyl sulfide is a clear flammable chemical compound with a pungent garlic-like odor. It has the chemical formula C 4H 10S, though it can also be written (C 2H 5) 2S or Et 2S to make its chemical structure more clear. It is prepared by treating ethanol with concentrated sulfuric acid, partially neutralizing the new solution with sodium carbonate, then distilling the resulting sodium ethyl sulfate in a solution containing potassium sulfide.
    Diethyl sulfide is a by-product of the commercial production of ethanethiol, which is prepared by the reaction of ethylene with hydrogen sulfide over an alumina-based catalyst. The amount of diethyl sulfide produced can be controlled by varying the ratio of hydrogen sulfide to ethylene.

    Basic Info

    Chemical Name diethyl sulfide
    Synonyms

    Ethyl thioether;
    Ethyl Sulfide;
    1,1'-Thiobisethane;
    Ethane, 1,1‘-thiobis-;
    diethyl-sulphide;
    Thioethyl ether;
    sulfure de diethyle;
    Diethyl sulfide;
    Diethyl Thioether;
    Diethylthioether;
    ethylsulfanylethane;
    Ethylthioethane;
    3-Thiapentane;
    Ethane,1,1'-thiobis;
    Ethyl monosulfide;

    CAS No. 352-93-2
    Molecular Formula C4H10S
    Molecular Weight 90.18720
    PSA 25.30000
    LogP 1.75940

    Properties

    Appearance & Physical State colourless liquid
    Density 0.83
    Boiling Point 90-92ºC
    Melting Point -103.8ºC
    Flash Point -10ºC
    Refractive Index 1.441-1.443
    Stability Stable. Highly flammable. Incompatible with strong oxidizing agents.
    Vapor Pressure 105 mm Hg ( 37.7 °C)

    Safety Info

    RTECS LC7200000
    Hazard Class 3
    Safety Statements S16
    HS Code 2930909090
    WGK Germany 3
    Packing Group II
    RIDADR UN 2375
    Risk Statements R11
    Hazard Codes F

    Synthesis Route

    Butyl Disulfide+hydroquinonediethyl sulfide+o,o-Diethyl S-butyl phosphorothioate
    Ethylthiocyanatediethyl sulfide+potassium thiocyanate
    iodoethaneDiethyl disulfide+diethyl sulfide

    Toxicity

    Exposure Route Type of Test Species Observed Dose/Duration Toxic Effects
    Administration onto the skin Standard Draize test Rodent - rabbit 20 mg/24H -
    Administration into the eye Standard Draize test Rodent - rabbit 500 mg/24H -

    Precursor

    Ethanol
    2-Chloroethyl ethyl sulfide
    methanethiol
    ethene

    Downstream Product

    1-Ethyl-1H-indole-3-carbaldehyde
    Benzophenone oxime
    Diethyl disulfide
    dimethyl 2-phenacylidenepropanedioate

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