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dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane

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Origin: China

Cas No: 1070663-78-3

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 50 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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CAS No.: 1070663-78-3 Formula: C35H53O2P Molecular Weight: 536.76800

Description

BrettPhos is used in cross C-N coupling reactions, acting as a biarylmonophosphine catalyst.

Basic Info

Chemical Name	dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane
Synonyms	2-(DICYCLOHEXYLPHOSPHINO)-3,6-DIMETHOXY-2'-4'-6'-TRI-I-PROPYL-1,1'-BIPHENYL; cyclohexyl BrettPhos; 2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl; 2-(3-METHOXYPROPOXY)-N-METHYL-1-PROPANAMINE; DICYCLOHEXYL(2',4',6'-TRIISOPROPYL-3,6-DIMETHOXYBIPHENYL-2-YL)PHOSPHINE; 2-DICYCLOHEXYLPHOSPHINO-2',4',6'-TRIISOPROPYL-3,6-DIMETHOXYBIPHENYL; BrettPhos; Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine;
CAS No.	1070663-78-3
Molecular Formula	C35H53O2P
Molecular Weight	536.76800
PSA	32.05000
LogP	10.51360

Synthesis Route

2-Iodo-2',4',6'-triisopropyl-3,6-dimethoxy-1,1'-biphenyl+Dicyclohexylchlorophosphine→dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane
Di-tert-butylchlorophosphane+→dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane
magnesium,1,3,5-tri(propan-2-yl)benzene-6-ide,bromide→dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane

Precursor

Di-tert-butylchlorophosphane

Dicyclohexylchlorophosphine
2-Iodo-2',4',6'-triisopropyl-3,6-dimethoxy-1,1'-biphenyl

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