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Picture of Dichloroacetic acid methyl ester

Dichloroacetic acid methyl ester

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Origin: China

Cas No: 116-54-1

Specification: 99%min

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  • Products Specification
  • Product Description
  • Property

    CAS No.: 116-54-1 Formula: C3H4Cl2O2 Molecular Weight: 142.96900

    Description

    Dichloroacetic Acid Methyl Ester is used in the preparation of telechelics and block copolymers through living radical polymerization.

    Basic Info

    Chemical Name Dichloroacetic acid methyl ester
    Synonyms

    Dichloroacetic Acid Methyl Ester;
    Methyl 2,2-dichloroacetate;
    C 12320200 Dichloroacetic;
    Acetic acid, dichloro-, methyl ester;
    Methyl dichloroacetate;

    CAS No. 116-54-1
    Molecular Formula C3H4Cl2O2
    Molecular Weight 142.96900
    PSA 26.30000
    LogP 0.96310

    Properties

    Appearance & Physical State A colorless liquid with an ethereal odor.
    Density 1.381
    Boiling Point 141-145ºC
    Melting Point -52ºC
    Flash Point 80ºC
    Refractive Index 1.4411-1.4431
    Water Solubility Slightly soluble
    Stability Stable under normal temperatures and pressures.
    Storage Condition Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.
    Vapor Pressure 5.5mmHg at 25°C

    Safety Info

    RTECS AG6625000
    Hazard Class 6.1(b)
    Safety Statements S26-S37/39
    HS Code 29154000
    Packing Group III
    WGK Germany 3
    RIDADR UN 2299
    Risk Statements R36/37/38
    Hazard Codes Xi

    Synthesis Route

    dichloroacetyl chloridedichloroacetic acid+Dichloroacetic acid methyl ester
    Methanol+chloromethyl 2,2-dichloroacetatechloromethanol+Dichloroacetic acid methyl ester
    dichloroacetyl chlorideDichloroacetic acid methyl ester

    GC Analysis

    Column type Active phase Temperature (°C) Retention Index (I) Temperature Control Method
    Capillary SE-30 100. 808. isothermal
    Capillary SE-30 120. 791. isothermal
    Capillary SE-30 140. 785. isothermal
    Capillary SE-30 80. 821. isothermal
    Capillary SE-30 100. 835. isothermal

    Precursor

    dichloroacetyl chloride
    dimethyl sulfate
    1,1,1,3,3-pentachloropropan-2-one
    dichloroacetic acid

    Downstream Product

    chloramphenicol palmitate
    methyl 1,3-benzodithiole-2-carboxylate
    METHYL 4-METHYL-2-PENTENOATE
    Methyl (2E)-3-(1,3-benzodioxol-5-yl)acrylate

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