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4-(dimethylamino)azobenzene

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Origin: China

Cas No: 60-11-7

Specification: 99%min

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  • Products Specification
  • Product Description
  • Property

    CAS No.: 60-11-7 Formula: C14H15N3 Molecular Weight: 225.28900

    Description

    Methyl yellow, or C.I. 11020, is a chemical compound which may be used as a pH indicator.
    Methyl yellow (pH indicator) below pH 2.9 above pH 4.0 2.9 ⇌ 4.0; In aqueous solution at low pH, methyl yellow appears red. Between pH 2.9 and 4.0, methyl yellow undergoes a transition, to become yellow above pH 4.0.

    Basic Info

    Chemical Name 4-(dimethylamino)azobenzene
    Synonyms

    Benzenamine, N,N-dimethyl-4-(phenylazo)-;
    Dimethyl yellow;
    Solvent Yellow 2;

    CAS No. 60-11-7
    Molecular Formula C14H15N3
    Molecular Weight 225.28900
    PSA 27.96000
    LogP 4.16800

    Properties

    Appearance & Physical State Orange powder
    Density 1.027g/cm3
    Boiling Point 371.05ºC at 760 mmHg
    Melting Point 111-117ºC
    Flash Point 178.205ºC
    Refractive Index 1.567
    Water Solubility 13.6 mg/L
    Stability Stable, but heat and light sensitive. Incompatible with strong oxidizing agents, strong acids.
    Storage Condition Store at RT.

    Safety Info

    RTECS BX7350000
    Hazard Class 6.1
    Safety Statements S36/37-S45
    HS Code 29270000
    WGK Germany 3
    Packing Group III
    RIDADR UN 2811
    Risk Statements R25; R40; R68
    Hazard Codes T

    Synthesis Route

    N-amino-N-phenylnitrous amide+N,N-dimethylanilinePhenyl azide+4-(dimethylamino)azobenzene
    Methyl Orange1,2-diphenyldiazene+4-[(4-aminophenyl)hydrazinylidene]cyclohexa-2,5-dien-1-one
    tri-N-methyl-4-phenylazo-anilinium, chlorideN,N-dimethylaniline+4-(dimethylamino)azobenzene

    GC Analysis

    Column type Active phase Temperature (°C) Retention Index (I) Temperature Control Method
    Capillary DB-5MS - 366.03 temperature ramp
    Capillary DB-5MS - 368.20 temperature ramp

    Toxicity

    Exposure Route Type of Test Species Observed Dose/Duration Toxic Effects
    Oral LD50 - Lethal dose, 50 percent kill Rodent - rat 200 mg/kg 1.Details of toxic effects not reported other than lethal dose value
    Intraperitoneal LD50 - Lethal dose, 50 percent kill Rodent - rat 230 mg/kg 1.Lungs, Thorax, or Respiration-dyspnea
    2.Lungs, Thorax, or Respiration-cyanosis
    Oral LD50 - Lethal dose, 50 percent kill Rodent - mouse 300 mg/kg 1.Details of toxic effects not reported other than lethal dose value

    Precursor

    1-(4-N,N'-dimethylaminophenyl)-1-propanol

    N,N-dimethylaniline
    N,N-dimethyl-4-phenyldiazenylbenzeneamine oxide

    Downstream Product

    N,N-dimethyl-4-[(3-nitrophenyl)diazenyl]aniline
    N,N-dimethyl-4-[(4-nitrophenyl)diazenyl]aniline
    N,N-dimethyl-1,4-phenylenediamine

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