Home > Chiral Compounds> (3aR,5S,6S,6aR)-6-hydroxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

(3aR,5S,6S,6aR)-6-hydroxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

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Origin: China

Cas No: 53167-11-6

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 100 mt/month

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CAS No.: 53167-11-6 Formula: C8H12O5 Molecular Weight: 188.17800

Description

1,2-O-Isopropylidene-alpha-D-xylo-pentodialdo-1,4-furanose was investigated as a possible reagent in the intramolecular cyclization of alkoxyamino-sugars in preparation of glycosidase inhibitors.

Basic Info

Chemical Name	(3aR,5S,6S,6aR)-6-hydroxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde
Synonyms	5-Aldo-1,2-O-isopropylidene-a-D-xylofuranose; 1,2-O-Isopropylidene-alpha-D-xylo-pentodialdo-1,4-furanose;
CAS No.	53167-11-6
Molecular Formula	C8H12O5
Molecular Weight	188.17800
PSA	64.99000
LogP	-0.57740

Synthesis Route

1,2-O-Isopropylidene-D-glucofuranose→(3aR,5S,6S,6aR)-6-hydroxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde
Diacetone-d-Glucose→(3aR,5S,6S,6aR)-6-hydroxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde
1,2-O-Isopropylidene-α-D-glucofuranose→(3aR,5S,6S,6aR)-6-hydroxy-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-5-carbaldehyde

Precursor

1,2-O-Isopropylidene-α-D-xylofuranose
Diacetone-d-Glucose
1,2-O-Isopropylidene-D-glucofuranose
diacetone-D-glucose

Downstream Product

1,2-O-Isopropylidene-α-D-xylofuranose
5-(2-hydroxyethyl)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-6-ol
5-ethenyl-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-6-ol

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