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Picture of (1s,4s)-Bbicyclo[2.2.1]hepta-2,5-diene


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Origin: China

CasNo: 121-46-0

specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 100 mt/month

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  • Products Specification
  • Description
  • Property

    CAS No.: 121-46-0 Formula: C7H8 Molecular Weight: 92.13840


    Norbornadiene is a bicyclic, hydrocarbon and an organic compound. Norbornadiene is of interest as a metal-binding ligand, whose complexes are useful for homogeneous catalysis. It has been intensively studied owing to its high reactivity and distinctive structural property of being a diene that cannot isomerize (isomers would be anti-Bredt olefins). Norbornadiene is also a useful dienophile in Diels-Alder reactions.

    Basic Info

    Chemical Name (1s,4s)-Bbicyclo[2.2.1]hepta-2,5-diene


    CAS No. 121-46-0
    Molecular Formula C7H8
    Molecular Weight 92.13840
    PSA 0.00000
    LogP 1.74850


    Appearance & Physical State A colorless liquid with a hydrocarbon odor.
    Density 0.906
    Boiling Point 89ºC
    Melting Point -19ºC
    Flash Point 12 °F
    Refractive Index 1.47
    Stability Unstable.
    Storage Condition Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Keep under a nitrogen blanket. Flammables-area.
    Vapor Pressure 2.617mmHg at 25°C

    Safety Info

    RTECS RB6535000
    Hazard Class 3
    Safety Statements S16-S23
    HS Code 29021990
    Packing Group II
    WGK Germany 2
    RIDADR UN 2251
    Risk Statements R11
    Hazard Codes F
    Hazard Declaration H225
    Caution Statement P210
    Signal Word Danger
    Symbol GHS02

    Synthesis Route

    bicyclo[2.2.1]hepta-2,5-diene,carbon monoxide,molybdenum+carbon monoxide(1s,4s)-Bbicyclo[2.2.1]hepta-2,5-diene+hexacarbonylmolybdenum

    GC Analysis

    Column type Active phase Temperature (°C) Retention Index (I) Temperature Control Method
    Capillary OV-101 100. 711. isothermal
    Capillary OV-101 80. 707. isothermal
    Capillary Squalane 100. 691.1 isothermal
    Capillary Squalane 80. 686.3 isothermal
    Capillary SE-54 100. 722.8 isothermal


    Exposure Route Type of Test Species Observed Dose/Duration Toxic Effects
    Inhalation LC50 - Lethal concentration, 50 percent kill Rodent - rat 14100 ppm/8H 1.Details of toxic effects not reported other than lethal dose value
    Intraperitoneal LD50 - Lethal dose, 50 percent kill Rodent - rat 890 mg/kg 1.Details of toxic effects not reported other than lethal dose value
    Oral LD50 - Lethal dose, 50 percent kill Rodent - mouse 3850 mg/kg 1.Details of toxic effects not reported other than lethal dose value


    exo-3-deuteriobicyclo[2.2.1]hept-5-enyl tosylate

    bicyclo(2.2.1)hepta-2,5-dien-2-yl p-tolyl sulfone

    Downstream Product

    4,7-Methano-1,3,2-benzodioxathiole, 3a,4,7,7a-tetrahydro-, 2,2-dioxide

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