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Home > Organosilicon Compounds> 1,5-Anhydro-2-deoxy-6-O-(triisopropylsilyl)-D-arabino-hex-1-enitol
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1,5-Anhydro-2-deoxy-6-O-(triisopropylsilyl)-D-arabino-hex-1-enitol

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Origin: China

Cas No: 137915-37-8

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 50 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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  • Products Specification
  • Product Description

  • Property

    CAS No.: 137915-37-8 Formula: C15H30O4Si Molecular Weight: 302.48200

    Basic Info

    Chemical Name 1,5-Anhydro-2-deoxy-6-O-(triisopropylsilyl)-D-arabino-hex-1-enitol
    Synonyms

    6-O-(Triisopropylsilyl)-D-glucal;
    (2R,3S,4R)-2-[tri(propan-2-yl)silyloxymethyl]-3,4-dihydro-2H-pyran-3,4-diol;
    6-O-Triisopropylsilyl-D-glucal;

    CAS No. 137915-37-8
    Molecular Formula C15H30O4Si
    Molecular Weight 302.48200
    PSA 58.92000
    LogP 2.81280

    Properties

    Density 0.726 g/mL at 25ºC(lit.)
    Boiling Point 361.886ºC at 760 mmHg
    Flash Point 113ºC
    Refractive Index n20/D 1.489(lit.)
    Vapor Pressure 0mmHg at 25°C

    Synthesis Route

    Triisopropylsilyl Chloride+(2R,3S,4R)-2-(hydroxymethyl)-3,4-dihydro-2H-pyran-3,4-diol→1,5-Anhydro-2-deoxy-6-O-(triisopropylsilyl)-D-arabino-hex-1-enitol
    Triisopropylsilyl Chloride+[(2R,3S,4R)-3,4-diacetyloxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate→1,5-Anhydro-2-deoxy-6-O-(triisopropylsilyl)-D-arabino-hex-1-enitol
    [(2R,3S,4R)-3,4-diacetyloxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate→1,5-Anhydro-2-deoxy-6-O-(triisopropylsilyl)-D-arabino-hex-1-enitol

    Precursor

    (2R,3S,4R)-2-(hydroxymethyl)-3,4-dihydro-2H-pyran-3,4-diol
    Triisopropylsilyl Chloride
    [(2R,3S,4R)-3,4-diacetyloxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate

    Downstream Product

    [(2R,3S,4R)-3-acetyloxy-2-[tri(propan-2-yl)silyloxymethyl]-3,4-dihydro-2H-pyran-4-yl] acetate
    3-O-BENZYL-1,2-O-ISOPROPYLIDENE-α-D-GLUCOFURANOSE

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