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Изображение (+)-Nootkatone

(+)-Nootkatone

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начало: Китай

Кас Но: 4674-50-4

Спецификация: 99%наименьший

минимальный объем заказа: 1 /kg

снабженческая способность: 100 mt/month

опережающий период: OEM 7 дней, пятно 3 дня

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  • Характеристики продукции
  • Описание продукта

  • Property

    CAS No.: 4674-50-4 Formula: C15H22O Molecular Weight: 218.33500

    Description

    Nootkatone is a natural organic compound and is the most important and expensive aromatic of grapefruit. It is a sesquiterpene and a ketone.
    Nootkatone was previously thought to be one of the main chemical components of the smell and flavour of grapefruits. In its solid form it is usually found as crystals. As a liquid, it is viscous and yellow. Nootkatone is typically extracted from grapefruit, but can also be manufactured with genetically modified organisms, or through the chemical or biochemical oxidation of valencene. It is also found in Alaska yellow cedar trees and vetiver grass.

    Basic Info

    Chemical Name (+)-Nootkatone
    Synonyms

    NOOTKATONE;

    CAS No. 4674-50-4
    Molecular Formula C15H22O
    Molecular Weight 218.33500
    PSA 17.07000
    LogP 3.90420

    Properties

    Appearance & Physical State viscous yellow liquid or crystals with a citrus odour; can be isolated from grapefruit
    Density 0.997
    Boiling Point 125ºC 0,5mm
    Melting Point 35-39ºC
    Flash Point 99ºC
    Refractive Index n20/D 1.52
    Stability Stable. Incompatible with strong oxidizing agents.

    Safety Info

    Safety Statements S24/25
    Symbol GHS07
    Hazard Declaration H317
    Caution Statement P280
    Signal Word Warning

    Synthesis Route

    (4R,4aS,6R)-4,4a,5,6,7,8-Hexahydro-4,4a-dimethyl-6-(1-chloro-1-methylethyl)-2(3H)-naphthalenone→(4R,4aS)-4,4a-dimethyl-6-propan-2-ylidene-4,5,7,8-tetrahydro-3H-naphthalen-2-one+(+)-Nootkatone
    (4R,4aS,6R)-4,4a,5,6,7,8-Hexahydro-4,4a-dimethyl-6-(1-chloro-1-methylethyl)-2(3H)-naphthalenone→(+)-Nootkatone
    (3R,4aR,5S)-4a,5-dimethyl-3-prop-1-en-2-yl-2,3,4,5,6,7-hexahydro-1H-naphthalene→phthalimide+(+)-Nootkatone

    Precursor

    (1R,3R,5R)-6,6-Dimethyl-3-(1-hydroxyethyl)bicyclo[3.1.1]heptan-2-one
    (1R,5R)-6,6-Dimethyl-2-[(trimethylsilyl)oxy]bicyclo[3.1.1]hept-2-ene
    (4R,4aS,6R)-4,4a,5,6,7,8-Hexahydro-4,4a-dimethyl-6-(1-chloro-1-methylethyl)-2(3H)-naphthalenone
    (3R,4aR,5S)-4a,5-dimethyl-3-prop-1-en-2-yl-2,3,4,5,6,7-hexahydro-1H-naphthalene

    Downstream Product

    (4R,4aS)-4,4a-dimethyl-6-propan-2-ylidene-4,5,7,8-tetrahydro-3H-naphthalen-2-one

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