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(+)-AROMADENDRENE

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Origin: China

CasNo: 489-39-4

specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 80 mt/month

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  • Products Specification
  • Description
  • Property

    CAS No.: 489-39-4 Formula: C15H24 Molecular Weight: 204.35100

    Basic Info

    Chemical Name (+)-AROMADENDRENE
    Synonyms

    alloaromadendrene;
    aromadenderene;
    aromandendrene;

    CAS No. 489-39-4
    Molecular Formula C15H24
    Molecular Weight 204.35100
    PSA 0.00000
    LogP 4.27090

    Properties

    Density 0.93g/cm3
    Boiling Point 261-263ºC(lit.)
    Melting Point 262ºC
    Flash Point 106.5ºC
    Refractive Index n20/D 1.497
    Storage Condition 2-8ºC

    Safety Info

    WGK Germany 3

    Synthesis Route

    ((1aR,4S,4aR,7R,7aR,7bS)-1,1,7-trimethyldecahydro-1H-cyclopropa[e]azulen-4-yl)methyl methanesulfonate(+)-AROMADENDRENE
    methyl (+)-(1S,7R)-8,8-dimethyl-3-oxobicyclo<5.1.0>octane-4-carboxylate(+)-AROMADENDRENE
    (+)-(1S,2S,4R,7R)-4-tert-butyldimethylsiloxymethyl-8,8-dimethyl-2-(2-propenyl)bicyclo<5.1.0>octan-3-one(+)-AROMADENDRENE

    GC Analysis

    Column type Active phase Temperature (°C) Retention Index (I) Temperature Control Method
    Capillary DB-1 150. 1455. isothermal
    Capillary DB-Wax - 1635. temperature ramp
    Capillary HP-5MS - 1440. temperature ramp
    Capillary DB-1 - 1439. temperature ramp
    Capillary HP-5 - 1441. temperature ramp

    Precursor

    (+)-(1R,2R,4R,7S)-7-tert-butyldimethylsiloxymethyl-3,3-dimethyltricyclo(6.3.0.02,4)undec-8-en-10-one
    (+)-(1S,2S,4R,7R)-4-tert-butyldimethylsiloxymethyl-8,8-dimethyl-2-(2-oxopropyl)bicyclo[5.1.0]octan-3-one
    (+)-(1S,2S,4R,7R)-4-tert-butyldimethylsiloxymethyl-8,8-dimethyl-2-(2-propenyl)bicyclo<5.1.0>octan-3-one
    ((1aR,4S,4aR,7R,7aR,7bS)-1,1,7-trimethyldecahydro-1H-cyclopropa[e]azulen-4-yl)methyl methanesulfonate

    Downstream Product

    (-)-GLOBULOL
    isoledene
    (+)-γ-GURJUNENE
    (1aR,4aR,7S,7aR,7bR)-1,1,7-Trimethyl-4-methylenedecahydro-1H-cycl opropa[e]azulen-7-ol

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