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spinosyn A

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Origin: China

Cas No: 131929-60-7

Specification: 99%min

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Supply Ability: 80 mt/month

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    CAS No.: 131929-60-7 Formula: C41H65NO10 Molecular Weight: 731.95500

    Description

    Spinosad is an insecticide based on chemical compounds found in the bacterial species Saccharopolyspora spinosa. The genus Saccharopolyspora was discovered in 1985 in isolates from crushed sugarcane which produce yellowish-pink aerial hyphae, with bead-like chains of spores enclosed in a characteristic hairy sheath. This genus is defined as aerobic, Gram-positive, nonacid-fast actinomycetes with fragmenting substrate mycelium. S. spinosa was isolated from soil collected inside a nonoperational sugar mill rum still in the Virgin Islands. Spinosad is a mixture of chemical compounds in the spinosyn family that has a generalized structure consisting of a unique tetracyclic ring system attached to an amino sugar (D-forosamine) and a neutral sugar (tri-Ο-methyl-L-rhamnose). Spinosad is relatively nonpolar and not easily dissolved in water.
    Spinosad is a novel mode-of-action insecticide derived from a family of natural products obtained by fermentation of S. spinosa. Spinosyns occur in over 20 natural forms, and over 200 synthetic forms (spinosoids) have been produced in the lab. Spinosad contains a mix of two spinosoids, spinosyn A, the major component, and spinosyn D (the minor component), in a roughly 17:3 ratio.

    Basic Info

    Chemical Name spinosyn A
    Synonyms

    RAMOPLANIN;
    SPINOSYN A;
    SPINOSAD;
    Spinosyn D;

    CAS No. 131929-60-7
    Molecular Formula C41H65NO10
    Molecular Weight 731.95500
    PSA 111.22000
    LogP 5.48740

    Properties

    Density 1.167 g/cm3
    Boiling Point 801.515ºC at 760 mmHg
    Melting Point 84ºC to 99.5ºC
    Flash Point 438.541ºC
    Refractive Index 1.54
    Vapor Pressure 0mmHg at 25°C

    Safety Info

    HS Code 2932209090
    Packing Group III
    RIDADR UN 3077

    Synthesis Route

    methyl 5-oxopentanoatespinosyn A
    spinosyn A
    (S)-5-Hydroxy-heptanoic acid methyl esterspinosyn A

    Precursor

    (S)-5-Hydroxy-heptanoic acid methyl ester
    (5S)-5-[tert-butyl(dimethyl)silyl]oxyheptanal

    13,14β-Dihydro A83543A aglycon 9α,17α-bis-O-(TBDMS) ether

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