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Methyl (Phenylthio)acetate

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Origin: China

Cas No: 17277-58-6

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 50 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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CAS No.: 17277-58-6 Formula: C9H10O2S Molecular Weight: 182.23900

Basic Info

Chemical Name	Methyl (Phenylthio)acetate
Synonyms	(Phenylthio)acetic Acid Methyl Ester; Methyl (phenylthio)acetate; methyl 2-phenylsulfanylacetate;
CAS No.	17277-58-6
Molecular Formula	C9H10O2S
Molecular Weight	182.23900
PSA	51.60000
LogP	1.95170

Properties

Density	1,17 g/cm3
Boiling Point	104ºC (4 torr)
Flash Point	115.3ºC
Refractive Index	n20/D 1.559
Vapor Pressure	0.013mmHg at 25°C

Safety Info

Safety Statements	S24/25
HS Code	2930909090
WGK Germany	3
Risk Statements	R20/21/22; R36/37/38
Hazard Codes	Xn

Synthesis Route

(2-acetyl-2-(methoxycarbonyl)hexyl)(phenyl)((trimethylsilyl)methyl)sulfonium trifluoromethanesulfonate→1-phenylsulfanylpropan-2-one+methyl 2-methylidenehexanoate
Trifluoro-methanesulfonate(2,2-bis-methoxycarbonyl-propyl)-phenyl-trimethylsilanylmethyl-sulfonium;→Methyl (Phenylthio)acetate+methyl methacrylate
Trifluoro-methanesulfonate(1-methoxycarbonyl-2-oxo-cycloheptylmethyl)-phenyl-trimethylsilanylmethyl-sulfonium;→2-methylidenecycloheptan-1-one+Methyl (Phenylthio)acetate

Precursor

methyl 2-(benzenesulfinyl)acetate
1-methoxy-1-trimethylsiloxyethene
thiophenol
2,3,5,6-tetramethyl-4-oxo-1-phenylthiocyclohexa-2,5-dienyl 2-chloroacetate

Downstream Product

methyl 2-(benzenesulfonyl)acetate
methyl 2-(benzenesulfinyl)acetate
Phenyl Disulfide
1-phenylsulfanylpropan-2-one

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