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Home > All categories> Commodity Chemicals> Organic Chemicals> Olefins> methyl (E)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate
Picture of methyl (E)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate

methyl (E)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate

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Origin: China

Cas No: 81703-93-7

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 100 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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  • Products Specification
  • Product Description

  • Property

    CAS No.: 81703-93-7 Formula: C9H14O4 Molecular Weight: 186.20500

    Basic Info

    Chemical Name methyl (E)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate
    Synonyms

    CAS No. 81703-93-7
    Molecular Formula C9H14O4
    Molecular Weight 186.20500
    PSA 44.76000
    LogP 0.86710

    Properties

    Density 1.079 g/mL at 25ºC(lit.)
    Boiling Point 260.961ºC at 760 mmHg
    Flash Point 204 °F
    Refractive Index n20/D 1.454(lit.)

    Safety Info

    WGK Germany 3

    Synthesis Route

    Ethyl (2E)-3-(2,2-dimethyl-1,3-dioxolan-4-yl)acrylate→(S)-(-)-5-Hydroxymethyl-2(5H)-Furanone+methyl (E)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate
    +(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde→methyl 3-(2,2-dimethyl-1,3-dioxolan-4-yl)prop-2-enoate+methyl (E)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate
    dimethyl methylphosphonoacetate+(R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde→methyl (E)-3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]prop-2-enoate

    Precursor

    dimethyl methylphosphonoacetate
    3-Methoxy-3-oxopropanoic acid
    Methyl diethylphosphonoacetate
    (R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxaldehyde

    Downstream Product

    methyl 3-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]propanoate
    (S)-4,5-ISOPROPYLIDENE-2-PENTENOL
    (S)-(-)-5-Hydroxymethyl-2(5H)-Furanone

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