Home > Organosilicon Compounds> (3aS,6R,6aS)-6-[(1S)-1-azido-2-[tert-butyl(dimethyl)silyl]oxyethyl]-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one

(3aS,6R,6aS)-6-[(1S)-1-azido-2-[tert-butyl(dimethyl)silyl]oxyethyl]-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one

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Origin: China

Cas No: 118464-49-6

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 100 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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CAS No.: 118464-49-6 Formula: C15H27N3O5Si Molecular Weight: 357.47700

Basic Info

Chemical Name	(3aS,6R,6aS)-6-[(1S)-1-azido-2-[tert-butyl(dimethyl)silyl]oxyethyl]-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one
Synonyms	5-azido-6-O-tert-butyldimethylsilyl-5-deoxy-2,3-O-isopropylidene-D-mannono-1,4-lactone; 5-azido-6-O-tert-butyldimethylsilyl-5-deoxy-2,3-O-isopropylidene-D-mannonolactone; 5-azido-5-deoxy-D-mannonolactone;
CAS No.	118464-49-6
Molecular Formula	C15H27N3O5Si
Molecular Weight	357.47700
PSA	103.74000
LogP	2.58536

Synthesis Route

6-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-L-gulonolactone→(3aS,6R,6aS)-6-[(1S)-1-azido-2-[tert-butyl(dimethyl)silyl]oxyethyl]-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one
(S)-2-((tert-butyldimethylsilyl)oxy)-1-((3aS,4S,6aS)-2,2-dimethyl-6-oxotetrahydrofuro[3,4-d][1,3]dioxol-4-yl)ethyl trifluoromethanesulfonate→(3aS,6R,6aS)-6-[(1S)-1-azido-2-[tert-butyl(dimethyl)silyl]oxyethyl]-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one
2,3:5,6-Di-O-isopropylidene-L-gulono-1,4-lactone→(3aS,6R,6aS)-6-[(1S)-1-azido-2-[tert-butyl(dimethyl)silyl]oxyethyl]-2,2-dimethyl-6,6a-dihydro-3aH-furo[3,4-d][1,3]dioxol-4-one

Precursor

L-gulono-1,4-lactone
6-O-tert-butyldimethylsilyl-2,3-O-isopropylidene-L-gulonolactone
(S)-2-((tert-butyldimethylsilyl)oxy)-1-((3aS,4S,6aS)-2,2-dimethyl-6-oxotetrahydrofuro[3,4-d][1,3]dioxol-4-yl)ethyl trifluoromethanesulfonate
2,3:5,6-Di-O-isopropylidene-L-gulono-1,4-lactone

Downstream Product

Kifunensine diacetonide
D-Manno-γ-lactam
2-Deoxy-1,3:4,5-di-O-isopropylidene-2-oxamoylamino-D-mannitol
Kifunensine,(5R,6R,7S,8R,8aS)-Hexahydro-6,7,8-trihydroxy-5-(hydroxymethyl)-imidazo[1,2-a]pyridine-2,3-dione

Hot tags: (3as,6r,6as)-6-[(1s)-1-azido-2-[tert-butyl(dimethyl)silyl]oxyethyl]-2,2-dimethyl-6,6a-dihydro-3ah-furo[3,4-d][1,3]dioxol-4-one, China, manufacturers, suppliers, factory, wholesale, low price, high quality