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[3-[2-[tert-butyl(dimethyl)silyl]oxyethyl]-4-oxoazetidin-2-yl] benzoate

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Origin: China

Cas No: 94944-10-2

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 50 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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CAS No.: 94944-10-2 Formula: C18H27NO4Si Molecular Weight: 349.49700

Basic Info

Chemical Name	[3-[2-[tert-butyl(dimethyl)silyl]oxyethyl]-4-oxoazetidin-2-yl] benzoate
Synonyms	4-benzyloxyazetidinone; [3-[2-[tert-butyl(dimethyl)silyl]oxyethyl]-4-oxidanylidene-azetidin-2-yl] benzoate; (3R,4R)-4-Benzoyloxy-3-([1-tert-butyldimethsilyloxy]ethyl)azetidin-2-one; [3-[2-[tert-butyl(dimethyl)silyl]oxyethyl]-4-oxo-azetidin-2-yl] benzoate; benzoic acid [3-[2-[tert-butyl(dimethyl)silyl]oxyethyl]-4-oxo-2-azetidinyl] ester; (3R,4R)-4-benzoyloxy-3-<(1R)-(1-tert-butyldimethylsiloxy)ethyl>-azetidin-2-one; (3S,4R)-4-Benzoyloxy-3-[(R)-1-(tert-butyldimethylsiloxy)ethyl]-2-azetidinone;
CAS No.	94944-10-2
Molecular Formula	C18H27NO4Si
Molecular Weight	349.49700
PSA	64.63000
LogP	3.65460

Synthesis Route

[3S-[3α(S*),4β]]-4-benzoyl-3-[1-[[[(1,1-dimethyl-ethyl)dimethyl]silyl]oxy]ethyl]-2-azetidinone→[3-[2-[tert-butyl(dimethyl)silyl]oxyethyl]-4-oxoazetidin-2-yl] benzoate
[3S-[3α(S*),4β]]-4-benzoyl-3-[1-[[[(1,1-dimethyl-ethyl)dimethyl]silyl]oxy]ethyl]-2-azetidinone→Cyclohexanone, 2-(2-oxiranylmethyl)-+[3-[2-[tert-butyl(dimethyl)silyl]oxyethyl]-4-oxoazetidin-2-yl] benzoate
benzenecarboperoxoic acid+(3S,4S)-3-<(R)-1'-(dimethyl-t-butylsilyloxy)ethyl>-4-oxoazetidine-2-carboxylic acid→[3-[2-[tert-butyl(dimethyl)silyl]oxyethyl]-4-oxoazetidin-2-yl] benzoate

Precursor

[3S-[3α(S*),4β]]-4-benzoyl-3-[1-[[[(1,1-dimethyl-ethyl)dimethyl]silyl]oxy]ethyl]-2-azetidinone
benzenecarboperoxoic acid
(3S,4S)-4-benzoyl-3-((R)-1-((tert-butyldimethylsilyl)oxy)ethyl)-1-(4-methoxyphenyl)azetidin-2-one
(3S,4S)-3-<(R)-1'-(dimethyl-t-butylsilyloxy)ethyl>-4-oxoazetidine-2-carboxylic acid

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