Home > Heterocyclic Compounds> 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-β-D-GLUCOSE

1-AZIDO-2,3,4,6-TETRA-O-ACETYL-β-D-GLUCOSE

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Origin: China

Cas No: 13992-25-1

Specification: 99%min

Min order Quantity: 1 /kg

Supply Ability: 100 mt/month

Lead time: 7 days for OEM, 3 days for ready goods

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Products Specification
Product Description

Property

CAS No.: 13992-25-1 Formula: C14H19N3O9 Molecular Weight: 373.31500

Description

β-D-Glucopyranosyl Azide 2,3,4,6-Tetraacetate, is an intermediate used for the synthesis of Protein Tyrosine Phosphatase 1B inhibito1. It is used for the preparation of variously coupled conjugates of D-glucose via click chemistry for inhibition of glycogen phosphorylase.

Basic Info

Chemical Name	1-AZIDO-2,3,4,6-TETRA-O-ACETYL-β-D-GLUCOSE
Synonyms	2,3,4,6-Tetra-O-acetyl-b-D-glucopyranosylazide; 2,3,4,6-TETRA-O-ACETYL-SS-D-GLUCOPYRANOSYL AZIDE; 2,3,4,6-Tetra-O-acetyl-D-glucopyranosyl azide; 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-B-D-GLUCOSE; acetic acid 3,4,5-triacetoxy-6-azido-tetrahydro-pyran-2-ylmethyl ester; 1-Azido-2,3,4,6-tetra-O-acetyl-D-glucose; 1-AZIDO-2,3,4,6-TETRA-O-ACETYL-SS-D-GLUCOSE;
CAS No.	13992-25-1
Molecular Formula	C14H19N3O9
Molecular Weight	373.31500
PSA	164.18000
LogP	-0.16744

Properties

Appearance & Physical State	beige solid.
Melting Point	127-131ºC(lit.)

Safety Info

Safety Statements	22-24/25
WGK Germany	3
RIDADR	UN 1325
Risk Statements	R2
Hazard Codes	Xi

Synthesis Route

[(2R,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(2,2,2-trichloroethanimidoyl)oxyoxan-2-yl]methyl acetate→2,3,4,6-Tetra-O-acetyl-β-D-glucose+1-AZIDO-2,3,4,6-TETRA-O-ACETYL-β-D-GLUCOSE
Beta-D-Glucose Pentaacetate→1-AZIDO-2,3,4,6-TETRA-O-ACETYL-β-D-GLUCOSE
2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl Bromide→1-AZIDO-2,3,4,6-TETRA-O-ACETYL-β-D-GLUCOSE

Precursor

2,3,4,6-TETRA-O-ACETYL-α-D-GLUCOPYRANOSYL CHLORIDE
Acetobromoglucose
Beta-D-Glucose Pentaacetate
2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl Bromide

Downstream Product

2,3,4,6-Tetra-O-acetyl-β-D-glucose
α-D(+)-Glucose pentaacetate
2,3,4,6-Tetra-O-acetyl-N-chloroacetyl-β-D-glucopyranosylamine
a-D-Glucopyranosylazide

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